# CoreChem:Balancing Chemical Equations

We have now determined symbols and formulas for all the ingredients of chemical equations, but one important step remains. We must be sure that the law of conservation of mass is obeyed. The same number of atoms (or moles of atoms) of a given type must appear on each side of the equation. This reflects our belief in Dalton’s third postulate that atoms are neither created, destroyed, nor changed from one kind to another during a chemical process. When the law of conservation of mass is obeyed, the equation is said to be balanced.

As a simple example of how to balance an equation, let us take the reaction which occurs when a large excess of mercury combines with bromine. In this case the product is a white solid which does not melt but instead changes to a gas when heated above 345°C. It is insoluble in water. From these properties it can be identified as mercurous bromide, Hg2Br2. The equation for the reaction would look like this:

Hg + Br2 → Hg2Br2      (1)

but it is not balanced because there are 2 mercury atoms (in Hg2Br2) on the right side of the equation and only 1 on the left.

An incorrect way of obtaining a balanced equation is to change this to

Hg + Br2HgBr2      (2)

This equation is wrong because we had already determined from the properties of the product that the product was Hg2Br2.Equation (2) is balanced, but it refers to a different reaction which produces a different product. The equation might also be incorrectly written as

Hg2 + Br2 → Hg2Br2      (3)

The formula Hg2 suggests that molecules containing 2 mercury atoms each were involved, but our previous microscopic experience with this element indicates that such molecules do not occur.

In balancing an equation you must remember that the subscripts in the formulas have been determined experimentally. Changing them indicates a change in the nature of the reactants or products. It is permissible, however, to change the amounts of reactants or products involved. For example, the equation in question is correctly balanced as follows:

2Hg + Br2 → Hg2Br2 (4)

The 2 written before the symbol Hg is called a coefficient. It indicates that on the microscopic level 2Hg atoms are required to react with the molecule. On a macroscopic scale the coefficient 2 means that 2 mol Hg atoms are required to react with 1 mol Br2 molecules. Twice the amount of Hg is required to make Hg2Br2 as we needed for HgBr2.

To summarize: Once the formulas (subscripts) have been determined, an equation is balanced by adjusting coefficients. Nothing else may be changed.

EXAMPLE 1 Balance the equation

Hg2Br2 + Cl2 → HgCl2 + Br2

Solution Although Br and Cl are balanced, Hg is not. A coefficient of 2 with HgCl2 is needed:

Hg2Br2 + Cl22HgCl2 + Br2

Now Cl is not balanced. We need 2 Cl2 molecules on the left:

Hg2Br2 + 2Cl2 → 2HgCl2 + Br2

We now have 2Hg atoms, 2Br atoms, and 4Cl atoms on each side, and so balancing is complete.

Most chemists use several techniques for balancing equations.1 For example, it helps to know which element you should balance first. When each chemical symbol appears in a single formula on each side of the equation (as Example 1), you can start wherever you want and the process will work. When a symbol appears in three or more formulas, however, that particular element will be more difficult to balance and should usually be left until last.

1Laurence E. Strong, Balancing Chemical Equations, Chemistry, vol. 47, no. 1, pp. 13-16, January 1974, discusses some techniques in more detail.

EXAMPLE 2 When butane (C4H10) is burned in oxygen gas (O2), the only products are carbon dioxide(CO2) and water. Write a balanced equation to describe this reaction.

Solution First write an unbalanced equation showing the correct formulas of all the reactants and products:

C4H10 + O2 → CO2 + H2O

We note that O atoms appear in three formulas, one on the left and two on the right. Therefore we balance C and H first. The formula C4H10 determines how many C and H atoms must remain after the reaction, and so we write coefficients of 4 for CO2 and 5 for H2O:

C4H10 + O24CO2 + 5H2O

We now have a total of 13 O atoms on the right-hand side, and the equation can be balanced by using a coefficient of $\tfrac{13}{2}$ in front of O2:

C4H10 + $\tfrac{13}{2}$O2 → 4CO2 + 5H2O

Usually it is preferable to remove fractional coefficients since they might be interpreted to mean a fraction of a molecule. (One-half of an O2 molecule would be an O atom, which has quite different chemical reactivity.) Therefore we multiply all coefficients on both sides of the equation by two to obtain the final result:

2C4H10 + 13O28CO2 + 10H2O

(Sometimes, when we are interested in moles rather than individual molecules, it may be useful to omit this last step. Obviously the idea of half a mole of O2 molecules, that is, 3.011 × 1023 molecules, is much more tenable than the idea of half a molecule.)

Another useful technique is illustrated in Example 2. When an element (such as O2) appears by itself, it is usually best to choose its coefficient last. Furthermore, groups such as NO3, SO4, etc., often remain unchanged in a reaction and can be treated as if they consisted of a single atom. When such a group of atoms is enclosed in parentheses followed by a subscript, the subscript applies to all of them. That is, the formula involves Ca(NO3)2 involves 1Ca, 2N and 2 × 3 = 6 O atoms.

EXAMPLE 3 Balance the equation

NaMnO4 + H2O2 + H2SO4 → MnSO4 + Na2SO4 + O2 + H2O

Solution We note that oxygen atoms are found in every one of the seven formulas in the equation, making it especially hard to balance. However, Na appears only in two formulas:

2NaMnO4 + H2O2 + H2SO4 → MnSO4 + Na2SO4 + O2 + H2O

as does manganese, Mn:

2NaMnO4 + H2O2 + H2SO42MnSO4 + Na2SO4 + O2 + H2O

We now note that the element S always appears with 4 O atoms, and so we balance the SO4 groups:

2NaMnO4 + H2O2 + 3H2SO4 → 2MnSO4 + Na2SO4 + O2 + H2O

Now we are in a position to balance hydrogen:

2NaMnO4 + H2O2 + 3H2SO4 → 2MnSO4 + Na2SO4 + O2 + 4H2O

and finally oxygen. (We are aided by the fact that it appears as the element.)

2NaMnO4 + H2O2 + 3H2SO4 → 2MnSO4 + Na2SO4 + 3O2 + 4H2O

Notice that in this example we followed the rule of balancing first those elements whose symbols appeared in the smallest number of formulas: Na and Mn in two each, S (or SO4) and H in three each, and finally O. Even using this rule, however, equations in which one or more elements appear in four or more formulas are difficult to balance without some additional techniques which we will develop when we investigate reactions in aqueous solutions.

The balancing of chemical equations has an important environmental message for us. If atoms are conserved in a chemical reaction, then we cannot get rid of them. In other words we cannot throw anything away. There are only two things we can do with atoms: Move them from place to place or from compound to compound. Thus when we "dispose" of something by burning it, dumping it, or washing it down the sink, we have not really gotten rid of it at all. The atoms which constituted it are still around someplace, and it is just as well to know where they are and what kind of molecule they are in. Discarded atoms in places where we do not want them and in undesirable molecules are known as pollution.